Synthesis of Kaempferol-3-0-(3",4'' -di-O-a-L-rhamnopyranosy^-^-D-galactopyranoside and its Comparison with the Natural Ascaside Isolated from Astragalus caucasicus

نویسندگان

  • Ingrid Riess-Maurer
  • Hildebert Wagner
  • András Lipták
چکیده

The trisaccharide, 3,4-di-0-(a-L-rhamnopyranosyl)-D-galactose was synthesized using benzyl 2,6-di-0-benzyl-/?-D-galactopyranoside as starting compound. Its acetobromo derivative was coupled with 4',7-di-O-benzyl-kaempferol. The structure of the synthetic kaempferol trioside was characterised by different spectroscopic methods (UV, IR, XH, 13C NMR and MS). Chromatographic and mass spectrometric comparison of the synthetic product with ascaside precluded their identity.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Kaempferol 3-0-[/J-D-Glucopyranosyl(l-2)/)-D-galactopyranoside], a New Flavonoid from Lilium candidum L

E. Nagy, I. Seres, and G. V erzár-Petri* Institute of Pharmacognosy, Sem m elweis Medical University, H-1450 Budapest, P. O. Box 91 A. Neszmelyi Central Research Institute for Chemistry of the Hungarian Academy of Sciences, H-1525 Budapest, P. O. Box 17, Hungary Z. Naturforsch. 39b, 1813-1815 (1984); received May 21, 1984 White Lily Flower, 3-0-[/?-D-Glucopyranosyl(l-2)/S-D-galactopyranoside]-k...

متن کامل

Anti-Psoriatic Activity of Flavonoids from the Bark of Givotia rottleriformis Griff. Ex Wight.

Givotia rottleriformis has been used in the indigenous systems of medicine for the treatment of inflammatory diseases like rheumatism and psoriasis. In order to evaluate this information, antipsoriatic activity of three flavonoids isolated from the ethanol extract of the bark of Givotia rottleriformis were investigated using in-vitro and in-vivo model, namely Rutin (I), Luteolin-7-O-β-D-Glucuro...

متن کامل

Allergy-preventive effects of Hibiscus mutabilis 'versicolor' and a novel allergy-preventive flavonoid glycoside.

Allergy-preventive activity was demonstrated for the MeOH extract (HM) of the petals of Hibiscus mutabilis L. 'versicolor' MAKINO in a continuing search for allergy-preventive substances from natural sources, using the in vivo assay method. This assay system uses monitoring of a decrease in the blood flow at the tail vein of mice subjected to hen egg-white lysozyme (HEL) sensitization. By bioas...

متن کامل

Extracts and compounds with anti-diabetic complications and anti-cancer activity from Castanea mollissina Blume (Chinese chestnut)

BACKGROUND Castanea mollissima Blume (Chinese chestnut), as a food product is known for its various nutrients and functional values to the human health. The present study was carried out to analyze the anti-diabetic complications and anti-cancer activities of the bioactive compounds present in C. mollissima. METHODS The kernels (CK), shells (CS) and involucres (CI) parts of C. Blume were extr...

متن کامل

A new flavonol glycoside from Hylomecon vernalis.

Purification of a MeOH extract from the aerial parts of Hylomecon vernalis Maxim. (Papaveraceae) using column chromatography furnished a new acetylated flavonol glycoside (1), together with twenty known phenolic compounds (2-21). Structural elucidation of 1 was based on 1D- and 2D-NMR spectroscopy data analysis to be quercetin 3-O-[4‴-O-acetyl-α-L-arabinopyranosyl]-(1‴→6″)-β-D-galactopyranoside...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2012